NASA SBIR 2017 Solicitation

FORM B - PROPOSAL SUMMARY


PROPOSAL NUMBER: 171 S1.08-9622
SUBTOPIC TITLE: Surface & Sub-surface Measurement Systems
PROPOSAL TITLE: A total Ammonium Reactor (NHxR) for In Situ Mobile Measurements: A Critical Tool to Understand Aerosol Formation

SMALL BUSINESS CONCERN (Firm Name, Mail Address, City/State/Zip, Phone)
Bubbleology Research International
1642 Elm Ave
Solvang, CA 93463 - 2613
(805) 683-3333

PRINCIPAL INVESTIGATOR/PROJECT MANAGER (Name, E-mail, Mail Address, City/State/Zip, Phone)
Dr. Ira Leifer
ira.leifer@bubbleology.com
1642 Elm Ave
Solvang, CA 93463 - 2613
(805) 683-3333

CORPORATE/BUSINESS OFFICIAL (Name, E-mail, Mail Address, City/State/Zip, Phone)
Dr Ira Leifer
ira.leifer@bubbleology.com
1642 Elm Ave
Solvang, CA 93463 - 2613
(805) 683-3333

Estimated Technology Readiness Level (TRL) at beginning and end of contract:
Begin: 3
End: 5

Technology Available (TAV) Subtopics
Surface & Sub-surface Measurement Systems is a Technology Available (TAV) subtopic that includes NASA Intellectual Property (IP). Do you plan to use the NASA IP under the award?
No

TECHNICAL ABSTRACT (Limit 2000 characters, approximately 200 words)
We will develop, demonstrate, and optimize a front-end ammonium reactor (NHxR) for the fast, precise, and accurate measurement of gas-phase ammonia (NH3) and particle-phase ammonium ion (NH4+) by fast, high-flow Cavity Enhanced Absorption Spectroscopy (CEAS). We address Focus Area 9, Sub Topic S1.08

Value Proposition: There is a need to measure the total atmospheric NHX load (NH3+NH4+), with significant ecosystem implications including eutrophication, air quality, and indirectly on atmospheric radiative balance. Current NH3 analyzers miss most of the atmospheric NH3 load, present as fine aerosols.

The Innovation: The front-end NH4+ reactor cycles between a line that passes gas phase NH3 to the CEAS analyzer, and then a line where NH4+ aerosols are converted to NH3. A key innovation is flow path material, for which the literature is confused, with significant differences between Teflon formulations (factor of 10 difference in adsorption for PFA versus PTFE by one study).

This fast, in situ, analyzers, will enable measurements at dramatically lower per sample cost and far greater data density than aerosol samplers. The ability to measure both NH3 and NH4+ sufficiently rapidly will allow characterization of the strong heterogeneity exhibited by these short-lived species with localized emissions.

The NHxR is developed in collaboration with Los Gatos Research, a major manufacturer of state-of-the-art trace gas analyzers with extensive market awareness and well-established clients. BRI retains intellectual property to the NHxR and will license the NHxR for manufacture, potentially by LGR. LGR partnership provides significant commercialization advantages. Dr. Leifer (BRI - Team leader), has led multi-institution, multiple-aircraft NASA campaigns. BRI conducts numerous field studies to solve real-world problems, field expertise that aids in solution-development to meet NASA and market needs.

POTENTIAL NASA COMMERCIAL APPLICATIONS (Limit 1500 characters, approximately 150 words)
The NHxR will interest research labs (academic, industry, agency labs), regulatory agencies (local, state, national agencies), and agriculture, specifically intensive husbandry and poultry operations. The NHxR will be commercially accessible (pricing comparable to typical air quality analyzers) requiring low technical expertise and minimal maintenance and calibration time. The envisioned applications are stationary air monitoring and mobile monitoring on automobiles and/or small airplanes.

Commercial agricultural interests include stationary applications in enclosed cow and poultry sheds where concentrations can be far higher than outside ambient - with just the NH3 load (neglecting NH4+) reaching 8 ppm in cattle houses, to 18 ppm in pig houses and to 30 ppm in poultry houses in Northern Europe. Human exposure limits are 25 ppm. Industry trends are for greater agricultural animal density, intensifying these problems. Although workers can wear masks, animals inhale the full atmospheric NHX load. Current analyzers are negatively biased, missing the NH4+ load. An NHxR-CEAS could actively modulate exhaust fans, thus improving worker conditions and livestock health and productivity.

Other NHxR opportunities include industrial stack emission monitoring (power plants, refineries) where ammonia is a waste product, but are not a first focus. Other opportunities exist by extension to other sticky gases, such as nitrogen dioxide / nitric acid and sulfur dioxide / sulfuric acid.

POTENTIAL NON-NASA COMMERCIAL APPLICATIONS (Limit 1500 characters, approximately 150 words)
A number of NASA satellite platforms are focused on aerosols for which the NHxR can help understand formation mechanisms as well as improving our understanding of the relationship between space-based NH3 retrievals from satellites like AIRS and IASI to total atmospheric ammonia (NHx) load, which is the parameter that impacts ecosystems. Current NASA orbital instruments measuring aerosol products include MODIS, VIIRS, CALIPSO, etc., which will be added to by future missions such as PACE and candidate missions like HySpIRI. In all cases, better understanding of aerosol formation mechanisms and size distributions will improve interpretation of satellite-derived aerosol optical depth, the relationship between environmental controls and aerosol formation (which impacts all other satellite products via atmospheric radiative transfer corrections) and ecosystem impacts.

Additionally, there could be future planetary applications. For example, future Titan atmospheric explorer missions where NH3 plays an important role in aerosol formation or even Jupiter's Great Red Spot where NH3 also is proposed to form aerosols. After miniaturization of the NHxR design, it could play a role in future space missions as a front end to a CEAS or other planetary science analyzer.

TECHNOLOGY TAXONOMY MAPPING (NASA's technology taxonomy has been developed by the SBIR-STTR program to disseminate awareness of proposed and awarded R/R&D in the agency. It is a listing of over 100 technologies, sorted into broad categories, of interest to NASA.)
Chemical/Environmental (see also Biological Health/Life Support)

Form Generated on 04-19-17 12:59